蔡称心教授
蔡称心,男,1966年11月出生,江苏溧水县人。南京师范大学化学与材料科学学院教授、博士生导师。江苏省新型动力电池重点实验室主任。
生平经历
1989年7月 南京师范大学化学系化学教育专业本科生毕业,获学士学位;
1992年7月 中国科学院长春应用化学研究所物理化学专业硕士研究生毕业,并获硕士学位;
1995年7月 南京大学化学化工学院分析化学专业博士研究生毕业,并获博士学位;
1995年8月以来在南京师范大学化学与材料科学学院任教,从事电化学的教学与科研工作,先后任讲师、 副教授、教授;
1999年8月—2000年5月 新加坡国立大学材料科学系博士后;
2000年6年—2001年5月 美国纽约市立大学皇后学院化学与生物化学系博士后;
2004年9月—2005年8月 美国纽约市立大学皇后学院化学与生物化学系访问学者;
2012年8月—2013年2月 美国亚利桑那大学化学与生物化学系访问学者。
曾获荣誉
国家教育部科技进步三等奖(合作);
中国高校自然科学一等奖(合作);
江苏省科技进步三等奖(2009年度);
南京师范大学双优奖;
南京师范大学第二届中青年骨干教师;
南京师范大学优秀研究生导师;
南京师范大学优秀教师;
2006年度教育部“新世纪优秀人才支持计划”获得者;
江苏省“333工程”第三层次首批中青年科学技术带头人培养对象。
研究方向
蛋白质分子的电子转移机制、蛋白质错误折叠机制与其功能的关系、疾病DNA的电化学检测及应用、单细胞分析及应用、能源电化学等。
近年科研项目
(1) 国家自然科学基金,蛋白质错误折叠机理及其电化学特性研究(21175067)
(2) 国家自然科学基金,基于酶直接电子转移的生物燃料电池阴、阳极催化剂的研究(20773067)
(3) 国家自然科学基金,纳米毛细管用于单细胞成像研究(20673057)
(4) 新世纪优秀人才支持计划,纳米毛细管用于单细胞分析(NECT-06-0508)
(5) 江苏高等学校优秀科技创新团队项目,纳米材料与电化学分子识别
获得专利
名称 |
专利号 |
年度 |
一种适配体诱导的Ag2S量子点的制备方法 |
201410220711.X |
2014年 |
基于氮掺杂碳层包裹的空心多孔氧化镍复合材料的锂离子电池及其制备方法 |
201310724013.9 |
2013年 |
纳米磷酸铁空心球锂离子电池及其制备方法 |
201110095104.1 |
2011年 |
氮掺杂碳层包裹的空心多孔氧化镍复合材料及其制备方法 |
201310723921.6 |
2013年 |
主要论著
主要论著 |
刊载 |
年度 |
Multidecker Sandwich Cluster VnBenn+1 (n = 1, 2, 3, 4) as a Polarizable Bridge for Designing 1D Second-Order NLO Chromophore: Metal−π Sandwich Multilayer Structure as a Particular Charge-Transfer Axis for Constructing Multidimensional NLO Molecules |
J. Phys. Chem. C |
2015年 |
Graphyne-supported single Fe atom catalysts for CO oxidation |
Phys. Chem. Chem. Phys., |
2015年 |
One-Step Electrodeposition of Polyallylamine-Functionalized Gold Nanodendrites and Their Application in Sensing |
ChemPlusChem |
2015年 |
Synthesis of magnetic Fe3O4–Au hybrids for sensitive SERS detection of cancer cells at low abundance |
J. Mater. Chem. B |
2015年 |
Designing activatable aptamer probes for simultaneous detection of multiple tumor-related proteins in living cancer cells |
Biosensors and Bioelectronics |
2015年 |
Immobilization and electrocatalysis of Ru(III) ions on phosphonate functionalized gold nanoparticles |
Electrochimica Acta |
2015年 |
G-quadruplex DNAzyme-based electrochemiluminescence biosensing strategy for VEGF165 detection: Combination of aptamer–target recognition and T7 exonuclease-assisted cycling signal amplification |
Biosensors and Bioelectronics |
2015年 |
Fluorescence quenching of graphene oxide combined with the site-specific cleavage of restriction endonuclease for deoxyribonucleic acid demethylase activity assay |
Analytica Chimica Acta |
2015年 |
Probing the anticancer-drug-binding-induced microenvironment alterations in subdomain IIA of human serum albumin |
Journal of Colloid and Interface Science |
2015年 |
Mechanistic Insight into the Facet-Dependent Adsorption of Methanol on a Pt3Ni Nanocatalyst |
J. Phys. Chem. C |
2015年 |
DNA strand-displacement-induced fluorescence enhancement for highly sensitive and selective assay of multiple microRNA in cancer cells |
Chem. Commun., |
2014年 |
Electrochemiluminescence signal amplification combined with a conformation-switched hairpin DNA probe for determining the methylation level and position in the Hsp53 tumor suppressor gene |
Chem. Commun. |
2014年 |
Highly sensitive methyltransferase activity assay and inhibitor screening based on fluorescence quenching of graphene oxide integrated with the site-specific cleavage of restriction endonuclease |
Chem. Commun. |
2014年 |
Highly enantioselective direct Michael addition of 1,3-dicarbonyl compounds to β-fluoroalkyl-α-nitroalkenes |
Tetrahedron |
2014年 |
Aptamer-functionalized graphene oxide for highly efficient loading and cancer cell-specific delivery of antitumor drug |
J. Mater. Chem. B |
2014年 |
Nitrogen/Carbon Atomic Ratio-Dependent Performances of Nitrogen-Doped Carbon-Coated Metal Oxide Nanocrystals for Anodes in Lithium-Ion Batteries |
ACS Appl. Mater. Interfaces |
2014年 |
Rare earth elements activate endocytosis in plant cells |
PNAS |
2014年 |
Graphdiyne as a metal-free catalyst for low-temperature CO oxidation |
Phys. Chem. Chem. Phys., |
2014年 |
Graphene oxide-induced conformation changes of glucose oxidase studied by infrared spectroscopy |
Colloids and Surfaces B: Biointerfaces |
2013年 |
Microscopic effects of the bonding configuration of nitrogen-doped graphene on its reactivity toward hydrogen peroxide reduction reaction |
Phys. Chem. Chem. Phys. |
2013年 |
Fluorescence Quenching of Graphene Oxide Integrating with the Site-Specific Cleavage of the Endonuclease for Sensitive and Selective MicroRNA Detection |
Anal. Chem., |
2013年 |
Electrochemical probing of the solution pH-induced structural alterations around the heme group in myoglobin |
Phys. Chem. Chem. Phys. |
2013年 |
High specific detection and near-infrared photothermal therapy of lung cancer cells with high SERS active aptamer–silver–gold shell–core nanostructures |
Analyst, |
2013年 |
Nonenzymatic electrochemical detection of glucose based on Pd1Pt3–graphene nanomaterials |
Journal of Electroanalytical Chemistry |
2013年 |
Catalytic signal amplification of gold nanoparticles combining with conformation-switched hairpin DNA probe for hepatitis C virus quantification |
Chem. Commun., |
2012年 |
Preparation of an Ultrahigh Aspect Ratio Anodic Aluminum Oxide Template for the Fabrication of Ni Nanowire Arrays |
Acta Physico-Chimica Sinica |
2012年 |
Fluorescence quenching of gold nanoparticles integrating with a conformation-switched hairpin oligonucleotide probe for microRNA detection |
Chem. Commun., |
2012年 |
Synthesis of graphene-supported hollow Pt–Ni nanocatalysts for highly active electrocatalysis toward the methanol oxidation reaction |
Electrochimica Acta |
2012年 |
Synthesis of hollow mesoporous Pt–Ni nanosphere for highly active electrocatalysis toward the methanol oxidation reaction |
Electrochemistry Communications |
2012年 |
Effects of guanidinium ions on the conformational structure of glucose oxidase studied by electrochemistry, spectroscopy, and theoretical calculations: towards developing a chemical-induced protein conformation assay |
Phys. Chem. Chem. Phys |
2012年 |
Signal Amplification of Graphene Oxide Combining with Restriction Endonuclease for Site-Specific Determination of DNA Methylation and Assay of Methyltransferase Activity |
Anal. Chem., |
2012年 |
cile synthesis of nitrogen-doped graphene for measuring the releasing process of hydrogen peroxide from living cells |
J. Mater. Chem. |
2012年 |
Aptamer-Guided Silver–Gold Bimetallic Nanostructures with Highly Active Surface-Enhanced Raman Scattering for Specific Detection and Near-Infrared Photothermal Therapy of Human Breast Cancer Cells |
Anal. Chem. |
2012年 |
Enhanced cathode performances of amorphous FePO4 hollow nanospheres with tunable shell thickness in lithium ion batteries |
Electrochemistry Communications |
2012年 |
Insight into the effects of graphene oxide sheets on the conformation and activity of glucose oxidase: towards developing a nanomaterial-based protein conformation assay |
Phys. Chem. Chem. Phys. |
2012年 |
Indirect electrocatalytic determination of choline by monitoring hydrogen peroxide at the choline oxidase-prussian blue modified iron phosphate nanostructures |
Biosensors & bioelectronics |
2012年 |
Effects of structure, composition, and carbon support properties on the electrocatalytic activity of Pt-Ni-graphene nanocatalysts for the methanol oxidation |
Applied catalysis. B, Environmental |
2012年 |
A graphene–amorphous FePO4 hollow nanosphere hybrid as a cathode material for lithium ion batteries |
Chem. Commun., |
2012年 |
An electrochemical approach for detection of DNA methylation and assay of the methyltransferase activity |
Chemical communications |
2011年 |
Enhancing the electrochemical reduction of hydrogen peroxide based on nitrogen-doped graphene for measurement of its releasing process from living cells |
Chemical communications |
2011年 |
Microwave-assisted synthesis of graphene-supported Pd1Pt3 nanostructures and their electrocatalytic activity for methanol oxidation |
Electrochimica Acta |
2011年 |
Electrochemical and Spectroscopic Studies on the Conformational Structure of Hemoglobin Assembled on Gold Nanoparticles |
The journal of physical chemistry. B |
2011年 |
Bimetallic Pt–Au nanocatalysts electrochemically deposited on graphene and their electrocatalytic characteristics towards oxygen reduction and methanol oxidation |
PCCP. Physical chemistry chemical physics |
2011年 |
Ultrasensitive and Selective Electrochemical Identification of Hepatitis C Virus Genotype 1b Based on Specific Endonuclease Combined with Gold Nanoparticles Signal Amplification |
Analytical chemistry |
2011年 |
[beta]-and [alpha]-Bi2O3 nanoparticles synthesized via microwave-assisted method and their photocatalytic activity towards the degradation of rhodamine B |
Materials letters |
2011年 |
Electrochemical and spectroscopic studies on the conformational structure of hemoglobin assembled on gold nanoparticles |
Biosensors & bioelectronics |
2011年 |
New Insights into the Effects of Thermal Treatment on the Catalytic Activity and Conformational Structure of Glucose Oxidase Studied by Electrochemistry, IR Spectroscopy, and Theoretical Calculation |
JOURNAL OF PHYSICAL CHEMISTRY B |
2010年 |
Low-Potential Detection of Endogenous and Physiological Uric Acid at Uricase-Thionine-Single-Walled Carbon Nanotube Modified Electrodes |
ANALYTICAL CHEMISTRY |
2010年 |
基于内切酶特异性剪切作用的HCV电化学检测方法 |
中国化学会 |
2010年 |
Electrochemical approach for the specific detection of hepatitis C virus based on site-specific DNA cleavage of BamHI endonuclease |
ANALYTICAL METHODS |
2010年 |
Direct electrochemistry of glucose oxidase assembled on graphene and application to glucose detection |
ELECTROCHIMICA ACTA |
2010年 |
Pd@Pt Core-Shell Nanostructures with Controllable Composition Synthesized by a Microwave Method and Their Enhanced Electrocatalytic Activity toward Oxygen Reduction and Methanol Oxidation |
JOURNAL OF PHYSICAL CHEMISTRY C |
2010年 |
Iron phosphate nanostructures synthesized by microwave method and their applications in biosensing |
NANOTECHNOLOGY |
2010年 |
Graphene-gold nanostructure composites fabricated by electrodeposition and their electrocatalytic activity toward the oxygen reduction and glucose oxidation |
ELECTROCHIMICA ACTA |
2010年 |
Electrochemical Approach for Detection of Extracellular Oxygen Released from Erythrocytes Based on Graphene Film Integrated with Laccase and 2,2-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) |
ANALYTICAL CHEMISTRY4 |
2010年 |
Effects of 1-butyl-3-methylimidazolium tetrafluoroborate on the oxidation of glucose catalyzed by glucose oxidase |
ELECTROCHIMICA ACTA |
2009年 |
Cerium phosphate nanotubes: synthesis, characterization and biosensing |
NANOTECHNOLOGY |
2009年 |
Detection of Glucose Based on Direct Electron Transfer Reaction of Glucose Oxidase Immobilized on Highly Ordered Polyaniline Nanotubes |
ANALYTICAL CHEMISTRY |
2009年 |
Polyaniline Nanofibers: Synthesis, Characterization, and Application to Direct Electron Transfer of Glucose Oxidase |
JOURNAL OF PHYSICAL CHEMISTRY C |
2009年 |
Effects of ionic liquids on enzymatic catalysis of the glucose oxidase toward the oxidation of glucose |
J. Phys. Chem. B |
2009年 |
Electrochemical detection of hepatitis C virus based on site-specific DNA cleavage of BamHI endonuclease |
Chem. Commun |
2009年 |
Detection of glucose based on direct electron transfer reaction of glucose oxidase immobilized on Highly Ordered Polyaniline Nanotubes |
Anal. Chem |
2009年 |
Nonenzymatic electrochemical detection of glucose based on palladium-single-walled carbon nanotube hybrid nanostructures |
Anal. Chem |
2009年 |
A glucose biosensor based on electrocatalytic oxidation of NADPH at single-walled carbon nanotubes functionalized with poly(nile blue A) |
JOURNAL OF ELECTROANALYTICAL CHEMISTRY |
2008年 |
Electrochemical Oxidation of Ammonia on Ir Anode in Potential Fixed Electrochemical Sensor |
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES |
2008年 |
基于单壁碳纳米管/聚耐尔兰修饰电极上NADPH电催化氧化的葡萄糖传感器的研制
|
中国化学会第26届学术年会新能源与能源化学分会场论文集 |
2008年 |
Electron transfer kinetics at polarized nanoscopic liquid/liquid interfaces |
J. Am. Chem. Soc |
2006年 |
第十三次全国电化学会议论文摘要集(下集) |
2005年 |
|
《中级化学实验》 |
南京师范大学出版社 |
2004年 |
碳纳米管促进氧化还原蛋白质和酶的直接电子转移 |
电化学 |
2004年 |
碳纳米管在分析化学中的应用 |
分析化学 |
2004年 |
碳纳米管电极上辣根过氧化物酶的直接电化学 |
化学学报 |
2004年 |
碳纳米管修饰电极上葡萄糖氧化酶的直接电子转移 |
中国科学B辑 |
2003年 |
南京师大学报(自然科学版) |
1999年 |
|
Mechanistic Study on Ascorbic Acid Oxidation at Activated Glassy Carbon Electrode |
南京师大学报(自然科学版) |
1999年 |
铁氰化铜修饰玻碳电极的制备及电化学性质(英文) |
南京师大学报(自然科学版) |
1998年 |
修饰微带金电极上细胞色素C电极过程的热力学研究 |
高等学校化学学报 |
1995年 |
聚硫堇修饰微带金电极的性质及对NADH的催化氧化 |
高等学校化学学报 |
1995年 |
纳米级金膜微电极的制作、表征及异相催化反应 |
分析化学 |
1995年 |
Electrochemical characteristics and application of thiophenol self-assembling monolayer modified gold electrode |
Chinese Science Bulletin |
1995年 |
细胞色素c在微带金电极上的直接电化学 |
化学学报 |
1995年 |
纳米级微带金电极上葡萄糖氧化酶的固定、性质及应用 |
化学学报 |
1995年 |
电解液添加成份对贮氢电极性能影响的初步研究 |
化学研究与应用 |
1995年 |
对插型阵列微带电极的制作及其电化学特性研究 |
高等学校化学学报 |
1995年 |
硫酚自组装单分子层修饰金电极的电化学特异性及其应用 |
科学通报 |
1995年 |
表面修饰对贮氢电极电化学性能的影响 |
化学研究与应用 |
1995年 |
快扫描循环伏安法及其在电化学中的应用 |
分析科学学报 |
1993年 |
贮氢电极的电化学研究(Ⅱ)——贮氢电极的交流阻抗研究 |
高等学校化学学报 |
1993年 |